Product ID:BIODEGRADABLE CITRUS DEGREASER 20 OZ SIZE,
MSDS Date:01/29/1992
FSC:7930
NIIN:00N039279
MSDS Number: BRKZL

PREMIER INDUSTRIAL CORP

4500 EUCLID AVE
CLEVELAND, OH 44103
US

Emergency Phone: 216-391-8300

Info Phone: 216-391-8300

Preparer: M.M.

Cage: 0HRN5

PREMIER INDUSTRIAL CORP

CLEVELAND, OH 44103 US

Telephone: 216-391-8300

Cage: 0HRN5

(ORAL RAT) 500

CAS: 111-76-2

RTECS: KJ8575000

Fraction By Weight: 5%

OSHA PEL S, 50 PPM

ACGIH TLV: S, 25 PPM; 9293

(ORAL RAT)500 MG/KG.

CAS: 74-98-6

RTECS: TX2275000

Fraction By Weight: 10%

OSHA PEL 1000 PPM

ACGIH TLV: SIMPLE ASPHYXIANT

CYCLOHEXENE, 1-METHYL-4-(1-METHYLETHENYL)-,

CAS: 5989-27-5

RTECS: GW6360000

Fraction By Weight: 30%

WATER (DEIONIZED)

CAS: 7732-18-5

RTECS: ZC0110000

Fraction By Weight: 40-50%

(ORAL RAT) >12000

CAS: 67-63-0

RTECS: NT8050000

Fraction By Weight: <5%

OSHA PEL 400 PPM;500 STEL

ACGIH TLV: 400 PPM;500 STEL

VOLATILE ORGANIC COMPOUNDS

RTECS: 9999999VO

Fraction By Weight: 49.1%

LD50 LC50 Mixture:NONE SPECIFIED BY MANUFACTURER.
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO
Health Hazards Acute and Chronic:CAUSES EYE IRRITATION. VAPORS IN HIGH
CONCENTRATION ARE ANESTHETIC & IRRITATE UPPER RESPIRATORY SYSTEM.
EXCESS INHALATION MAY CAUSE DIZZINESS, GIDDINESSS, AND NAUSEA. MAY
CAUSE IRRITATION OF SKIN. PRO LONGED & REPEATED INHALATION MAY BE
HARMFUL TO RESPIRATORY SYSTEM, LIVER, KIDNEYS, CNS. ANIMAL STUDIES
(EFTS OF OVEREXP)
Explanation of Carcinogenicity:NOT RELEVANT.
Effects of Overexposure:HLTH HAZ:CLEARLY DEMONSTRATED DOSE-RELATED
ADVERSE EFFECTS ON THE CNS, HEMATOPOIETIC TISSUE, BLOOD, KIDNEYS
AND LIVER ASSOCIATED WITH THE ADMINISTRATION OF ETHYLENE GLYCOL
MONOBUTYL ETHER (EGBE) (EXTR ACTED FROM DHHS (NIOSH) PUBLICATION
NO.90-118) .
Medical Cond Aggravated by Exposure:NONE SPECIFIED BY MANUFACTURER.

First Aid:EYE:IMMEDIATELY FLUSH WITH PLENTY OF WATER FOR AT LEAST 15
MINUTES AND CALL MD. SKIN:WASH THOROUGHLY WITH PLENTY OF WATER AND
SOAP. INHAL:REMOVE TO FRESH AIR, ADMINISTER OXYGEN AND CALL MD.
INGEST:GET MD IMMEDIATELY. SHOW MSDS OR LABEL. DONOT INDUCE
VOMITING.

Flash Point:SUPP DATA
Lower Limits:0.6%
Extinguishing Media:WATER, FOG, FOAM, CO*2, DRY CHEMICAL.
Fire Fighting Procedures:WEAR NOISH/MSHA APPROVED SCBA & FULL
PROTECTIVE EQUIPMENT .
Unusual Fire/Explosion Hazard:EXPOSURE TO FIRE, HEAT OR PROLONGED
SUNLIGHT MAY CAUSE BURSTING. IF USED IN CONFINED SPACES, HAZARDOUS
VAPORS MAY SPREAD, BURN OR BUILD UP IN LOW AREAS.

Spill Release Procedures:REMOVE ALL IGNITION SOURCES. VENTILATE THE
AREA. WEAR NIOSH/MSHA APPROVED RESPIRATORY PROTECTION, PROTECTIVE
CLOTHING, GLOVES, AND EYE/FACE PROTECTION. CLEAN UP WITH ABSORBENT
MATERIAL. CONTAIN & PICK UP WASTE MATERIALS. PUT IN A SEALED
CONTAINER.
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.

Handling and Storage Precautions:AVOID EXPOSURE TO FIRE, HEAT, OR
PROLONGED SUNLIGHT. USE ONLY IN WELL VENTILATED AREAS. AVOID
PRLNGD/REPEATED BREATHING OF GAS,FUMES VAP/SPRAY MIST.
Other Precautions:AVOID PRLNGD/RPTD SKIN CNTCT. DO NOT TAKE INTERNALLY.
IN CASE OF ACCIDENT OR ILLNESS, GET MD IMMED & SHOW LABEL/MSDS.
KEEP OUT OF REACH OF CHILDREN. ALWAYS READ & FOLLOW DIRECTIONS ON
PROD LABEL. ADDI TIONAL TECHNICAL DATA SHEETS (SUPP DATA)

Respiratory Protection:USE ONLY IN WELL VENTILATED AREAS. IF
VENTILATION IS INADEQUATE, WEAR NIOSH/MSHA APPROVED RESPRIATORY
EQUIPMENT.
Ventilation:LOCAL:RECOMMENDED. MECHANICAL:REQUIRED.
Protective Gloves:SOLVENT RESISTANT GLOVES.
Eye Protection:SAFETY GLASSES.
Other Protective Equipment:NONE SPECIFIED BY MANUFACTURER.
Work Hygienic Practices:WASH THOROUGHLY AFTER HANDLING.
Supplemental Safety and Health
BOILING PT:PROPELLANT <0F, <-18C. FLASH PT:PROPELLANT <20F, <-7C. OTHER
PREC:AND/OR MSDS ARE AVAILABLE UPON REQUEST. FOR PROFESSIONAL AND
INDUSTRIAL USE ONLY.

Boiling Pt:B.P. Text:SUPP DATA
Vapor Density:>1
Evaporation Rate & Reference:<1 (ETHER=1)
Appearance and Odor:CLEAR LIQUID AEROSOL WITH CITRUS ODOR
Percent Volatiles by Volume:49

Stability Indicator/Materials to Avoid:YES
STRONG ACIDS.
Stability Condition to Avoid:AVOID EXPOSURE TO FIRE, HEAT, OR PROLONGED
SUNLIGHT.
Hazardous Decomposition Products:PYROLYSIS PRODUCTS.

Waste Disposal Methods:DO NOT PUNCTURE OR BURN CONTAINERS. DISPOSE OF
WASTES IN ACCORDANCE WITH FEDERAL, STATE AND LOCAL REGULATIONS.

Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.